张晓磊

职 称:特聘研究员

所在系所:材料化学系

个人主页:

E-MAIL:xiaolei.zhang@xjtu.edu.cn

专业方向:含硼材料化学与绿色合成

研究领域或方向

含硼有机光伏材料的设计与性质测试;

含硼同位素下游材料的开发与应用;

功能材料的绿色合成与可降解材料的开发;

工作经历

2023-       304永利集团官网入口,材料科学与工程学院,特聘研究员

2019-2022  德国维尔茨堡大学,博士后研究员(入选洪堡学者)

2018-2019  新加坡南洋理工大学,博士后研究员

2016-2019  江南大学,助理研究员

2014-2015  南京大学-苏州诺华制药有限公司联合招收,博士后研究员

教育经历

2009-2014  南京大学,化学化工学院,博士

2005-2009  南京大学,匡亚明学院,学士

科研项目

304永利集团官网入口青年拔尖人才支持计划(2023-2029)

国家自然科学基金青年项目(2017-2019)

发表论文:

1.X. Zhang,* F. Rauch, J. Niedens, R. B. da Silva, A. Friedrich, A. Nowak-Król,* S. J. Garden,* T. B. Marder,* Electrophilic C−H Borylation of Aza[5]helicenes Leading to Bowl-Shaped Quasi-[7]Circulenes with Switchable Dynamics. J. Am. Chem. Soc. 2022, 144, 22316. (highlighted by ChemistryViews (titled by Quasi-[7]Circulenes Prepared from Aza[5]helicenes, 2022-11-22) and Synfacts, 19: 0243 (2023). DOI: 10.1055/s-0042-1753326)

2.X. Zhang,* A. Friedrich, T. B. Marder,* Copper-Catalyzed Borylation of Acyl Chlorides with an Alkoxy Diboron Reagent: A Facile Route to Acylboron Compounds. Chem. Eur. J. 2022, 28, e202201329.

3.H.-J. Cao, W. Wei, F. Sun, X. Zhang,* C. Lu,* H. Yan,* Metal-Catalyzed B–H Acylmethylation of Pyridylcarboranes: Access to Carborane-Fused Indoliziniums and Quinoliziniums. Chem. Sci. 2021, 12, 15563.

4.H.-J. Cao, M. Chen, F. Sun, Y. Zhao, C. Lu, X. Zhang,* Z. Shi,* H. Yan,* Variable Metal Chelation Modes and Activation Sequence in Pd-Catalyzed B–H Poly-arylation of Carboranes. ACS Catal. 2021, 11, 14047.

5.X. Zhang, Q. Chen, R. Song, J. Xu, W. Tian,* S. Li, Z. Jin, Y. R. Chi,* Carbene-Catalyzed α,γ-Deuteration of Enals under Oxidative Conditions. ACS Catal. 2020, 10, 5475.

6.Z. Yang, W. Zhao, W. Liu, X. Wei, M. Chen, X. Zhang, X. Zhang,* Y. Liang,* C. Lu,* H. Yan,* Metal-Free Oxidative B−N Coupling of nido-Carborane with N-Heterocycles. Angew. Chem. Int. Ed. 2019, 58, 11886.

7.X. Zhang, H. Yan,* Metal-induced Selective B–H Functionalization of o-Carborane. Coord. Chem. Rev. 2019, 378, 466.

8.X. Zhang,* H. Yan,* Pd(II)-Catalyzed Synthesis of Bifunctionalized Carboranes via Cage B−H Activation of 1-CH2NH2-o-carboranes. Chem. Sci. 2018, 9, 3964.

9.X. Zhang,* H. Zheng, J. Li,* F. Xu, J. Zhao, H. Yan,* Selective Catalytic B−H Arylation of o‑Carboranyl Aldehydes by a Transient Directing Strategy. J. Am. Chem. Soc. 2017, 139, 14511.

10.X. Zhang, H. Dai, H. Yan,* W. Zou, D. Cremer,* B−H···π Interaction: A New Type of Nonclassical Hydrogen Bonding. J. Am. Chem. Soc. 2016, 138, 4334. (JACS cover, highlighted by C&EN (March 7, 2016), Chemistry Word (March 17, 2016))

11.X. Zhang, Z. Zhou, H. Yan,* Metal–metal Redox Synergy in Selective B–H Activation of ortho-Carborane-9,12-dithiolate. Chem. Commun. 2014, 50, 13077.

12.X. Zhang, X. Zou, H. Yan,* Synthesis of Boron-Fused 1,4-Dithiin via Cobalt-Mediated Disulfuration of Alkyne at the o-Carborane-9,12-dithiolate Unit. Organometallics 2014, 33, 2661.

13.X. Zhang, X. Tang, J. Yang, Y. Li, H. Yan,* V. I. Bregadze,* Boron-Substituted o-Carboranetrithiol To Construct Trimeric Cobalt Clusters. Organometallics 2013, 32, 2014.